Nd
As mentioned in the Maxwell Materials page, the Nd is the index of refraction of the material. The name Nd is used because it is the common way to denote an index of refraction that has been measured at the wavelength of 583 nm for a certain material. You can find a list of common IOR values here. The Nd is important not only for transparent materials but for all materials as it defines both surface reflections and the refraction of light inside the object.
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For opaque shiny materials (low roughness), an Nd of at least 3 is recommended if you want them to be overall reflective (no Fresnel falloff). To mimic a metallic material the Nd needs to be even higher. The Nd setting can go as high as 1000. For a mirror-like surface it is usually enough to set the Nd to 100.
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Force Fresnel
The amount of light that is reflected back from the object is determined by the refl 0° and 90° colors. The Nd controls the Fresnel curve, or the influence of these two colors, depending on viewing angle. In reality however, the Nd itself specifies how much light is reflected back from the surface, with a higher Nd specifying a more reflective material. These three settings (refl0°, refl90°, Nd) can come into conflict when you put in, for example, a black refl 0° color but a very high Nd. Force Fresnel ensures that the reflectance ramp (curve) between Ref0 and Ref90 will be maintained by the given Nd. It discards the luminance of a given reflectance color and enforces physically correct Fresnel while only deriving the hues of the refl. 0° and refl. 90° color chips.
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The Nd has no influence on the look of the material when working with Lambertian materials. Lambertian is a special mode which makes a surface reflect all light in a diffuse way (its roughness is 100). It is the highest roughness a surface can have. It is also important to remember that the Nd has less influence on the reflectance of an object the higher you set the Roughness and instead it's the Reflectance colors that matter more and more. You will see the biggest changes to the reflectiveness of the object as you change the Nd, when the surface roughness is low.
K parameter
From a physical point of view, the index of refraction is not just a plain number. In fact it is a number derived from a complex calculation to define the refractive index at one particular wavelength. This is the calculation:
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