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The settings for "Fluid_Oil" with low "Density" and increased "Viscosity". "Surface tension" creates drops.

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Alternatives

If the result with  "Liquid - PBD" fluids it might happen that the simulation fluid does not meet your expectations , esp. with water and foam or oil in water. We therefore recommend using the you can also try to redo the simulation with  "Liquid - SPH" type for these kinds of simulations.The simulation will take longer, but with much better results.

 

Result from the scene above. Water mixes with oil and creates drops during the separation process.